Bench height (m) | Horizon | pH | Organic C (%) | Fet Total Fe (g kg−1) | Fed Free Fe (g kg−1) | Fed/Fet Fe freed (%) | Feo Non-crystalline free Fe (g kg−1) | Fed - Feo Crystalline free Fe (g kg−1) | (Fed –Feo)/Fed Crystallinity of free Fe (%) | Alt Total Al (g kg−1) | Ald Free Al (g kg−1) | Ald/Alt Al freed (%) | Alo Non- crystalline free Al (g kg−1) | Ald - Alo Crystalline free Al (g kg−1) | (Ald –Alo)/Ald Crystallinity of free Al (%) |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
15 | A | 8.05 | 6.88 | 15.8 | 3.69 | 23 | 1.43 | 2.26 | 61 | 25.3 | 1.81 | 7 | 2.89 | − 1.08 | – |
 | C1 | 8.39 | 3.96 | 12.3 | 3.24 | 26 | 1.19 | 2.05 | 63 | 20.3 | 1.85 | 9 | 2.64 | − 0.79 | – |
 | C2 | 7.77 | 4.14 | 11.3 | 2.77 | 25 | 1.06 | 1.71 | 62 | 19.9 | 1.74 | 9 | 2.31 | − 0.57 | – |
 | C3 | 8.54 | 2.21 | 6.48 | 1.15 | 18 | 0.67 | 0.48 | 42 | 12.4 | 1.18 | 9 | 1.12 | 0.06 | 5 |
20 | A | 7.29 | 5.60 | 29.0 | 6.90 | 34 | 3.49 | 3.41 | 49 | 90 | 10.3 | 11 | 16.5 | − 6.2 | – |
 | Bw | 6.79 | 0.79 | 23.0 | 5.80 | 25 | 3.15 | 2.65 | 46 | 71 | 6.72 | 9 | 2.49 | 4.23 | 63 |
 | BC | 6.84 | 0.19 | nd | 5.82 | – | 5.42 | 0.40 | 7 | nd | 2.69 | – | 2.99 | − 0.30 | – |
 | C | 7.10 | 0.11 | 30.0 | 3.68 | 12 | 5.06 | − 1.38 | – | 71 | 1.66 | 2 | 1.91 | − 0.25 | – |
50 | A | 5.16 | 2.36 | 74.9 | 42.2 | 56 | 6.05 | 36.2 | 86 | 80.3 | 10.6 | 13 | 5.06 | 5.5 | 52 |
 | Bt | 5.00 | 1.61 | 73.8 | 46.8 | 63 | 6.97 | 39.8 | 87 | 88.2 | 10.8 | 13 | 6.00 | 4.8 | 44 |
 | 2 A | 5.28 | 2.56 | 69.7 | 47.1 | 68 | 13.6 | 33.5 | 71 | 68.7 | 11.8 | 17 | 6.89 | 5.0 | 42 |
 | 2Bt | 5.07 | 1.57 | 81.0 | 58.3 | 72 | 5.98 | 52.3 | 90 | 81.7 | 14.2 | 17 | 6.50 | 7.7 | 54 |
 | 2 C | 4.61 | 0.23 | 67.0 | 36.0 | 46 | 8.27 | 27.7 | 77 | 108 | 9.53 | 9 | 8.43 | 1.1 | 11 |
90 | A | 5.04 | 3.28 | 64.5 | 22.0 | 34 | 4.72 | 17.7 | 80 | 53.4 | 4.39 | 8 | 4.11 | 0.28 | 6 |
 | AB | 5.28 | 2.50 | 63.5 | 49.5 | 78 | 5.72 | 43.8 | 88 | 63.4 | 10.3 | 16 | 4.96 | 5.3 | 51 |
 | Bt1 | 5.18 | 1.73 | 77.8 | 51.0 | 66 | 4.68 | 46.3 | 91 | 84.0 | 9.79 | 12 | 4.68 | 5.11 | 52 |
 | Bt2 | 5.28 | 1.30 | 69.6 | 46.4 | 67 | 5.18 | 41.2 | 89 | 63.8 | 8.83 | 14 | 4.58 | 4.25 | 48 |
 | BC | 5.16 | 0.30 | 78.4 | 33.9 | 43 | 4.92 | 29.0 | 86 | 84.5 | 6.90 | 8 | 4.87 | 2.03 | 33 |
100 | A | 6.44 | 2.73 | 59.3 | 35.2 | 59 | 4.34 | 30.9 | 88 | 84.3 | 7.65 | 9 | 3.31 | 4.32 | 56 |
 | AB | 7.42 | 2.01 | 53.7 | 38.1 | 71 | 4.75 | 33.3 | 87 | 74.0 | 7.91 | 11 | 3.36 | 4.55 | 57 |
 | Bt1 | 7.44 | 0.77 | 62.0 | 46.2 | 75 | 2.68 | 43.5 | 94 | 81.7 | 9.23 | 11 | 3.33 | 5.90 | 64 |
 | Bt2 | 7.15 | 0.88 | 59.6 | 48.2 | 81 | 2.54 | 45.7 | 95 | 64.2 | 10.9 | 17 | 4.38 | 6.52 | 60 |
 | BC | 6.90 | 0.31 | 44.8 | 23.7 | 53 | 1.38 | 22.3 | 94 | 71.5 | 6.47 | 9 | 3.54 | 2.93 | 45 |
170 | O/A | 4.02 | 2.84 | 68.1 | 41.7 | 61 | 2.62 | 39.1 | 94 | nd | 12.9 | – | 3.60 | 9.30 | 72 |
 | Bt1 | 4.52 | 0.82 | 76.5 | 48.7 | 64 | 1.62 | 47.1 | 97 | 89.8 | 10.5 | 12 | 3.28 | 7.22 | 69 |
 | Bt2 | 4.69 | 0.76 | 75.5 | 46.7 | 62 | 1.40 | 45.3 | 97 | 93.0 | 11.4 | 12 | 3.50 | 7.90 | 69 |
 | Bt3 | 4.81 | 0.60 | 75.8 | 44.8 | 59 | 1.35 | 43.4 | 97 | 90.5 | 12.1 | 13 | 3.56 | 8.54 | 58 |
 | Bt4 | 4.62 | 0.54 | 73.5 | 43.1 | 59 | 1.62 | 41.6 | 97 | 97.8 | 10.7 | 11 | 3.85 | 6.85 | 64 |
 | C | 4.62 | 0.25 | 58.6 | 23.1 | 39 | 1.85 | 21.3 | 92 | 101 | 5.66 | 6 | 3.42 | 2.24 | 40 |
190 | A | 6.01 | 7.80 | nd | 44.1 | – | 9.72 | 34.4 | 78 | 51.3 | 15.2 | 30 | 9.14 | 6.06 | 40 |
 | 2Bt1 | 4.75 | 1.32 | 68.6 | 61.3 | 89 | 9.51 | 51.8 | 85 | 78.0 | 13.1 | 17 | 4.97 | 8.13 | 62 |
 | 2Bt2 | 4.65 | 1.05 | 71.5 | 69.8 | 97 | 5.61 | 64.2 | 92 | 77.7 | 14.0 | 18 | 4.22 | 9.78 | 70 |
 | 2Bt3 | 4.56 | 0.80 | 78.3 | 60.3 | 77 | 5.19 | 55.1 | 91 | 96.3 | 18.7 | 19 | 4.37 | 14.3 | 76 |
240 | A | 4.78 | 7.40 | 93.9 | 82.2 | 88 | 6.53 | 75.7 | 92 | 60.8 | 20.2 | 33 | 4.40 | 15.8 | 78 |
 | Bt1 | 4.62 | 1.25 | 94.8 | 54.9 | 58 | 4.93 | 50.0 | 91 | 97.2 | 11.5 | 12 | 4.79 | 6.71 | 58 |
 | Bt2 | 4.71 | 0.86 | 77.2 | 57.4 | 74 | 3.20 | 54.2 | 95 | 71.6 | 12.1 | 17 | 4.65 | 7.45 | 62 |
 | BC | 4.62 | 0.53 | 98.9 | 55.9 | 57 | 2.71 | 53.2 | 95 | 89.5 | 11.3 | 13 | 4.44 | 6.86 | 61 |